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The C-diazeniumdiolate (N-nitrosohydroxylamine) group in the amino acid graminine (Gra) is a newly discovered Fe(III) ligand in microbial siderophores. Graminine was first identified in the siderophore gramibactin, and since this discovery, other Gra-containing siderophores have been identified, including megapolibactins, plantaribactin, gladiobactin, trinickiabactin (gramibactin B), and tistrellabactins. The C-diazeniumdiolate is photoreactive in UV light which provides a convenient characterization tool for this type of of siderophores. This report details the process of genomics-driven identification of bacteria producing Gra-containing siderophores based on selected biosynthetic enzymes, as well as bacterial culturing, isolation and characterization of the C-diazeniumdiolate siderophores containing Gra. 

The circulation response to climate change shapes regional climate and extremes. Over the last decade an increasing number of atmospheric circulation signals have been documented, with some attributed to human activities. The circulation signals represent an exciting opportunity for improving our understanding of dynamical mechanisms, testing our theories and reducing uncertainties. The signals have also presented puzzles that represent an opportunity for better understanding the circulation response to climate change, its contribution to climate extremes, interactions with moisture, and connection to thermodynamic discrepancies. The next decade is likely to be a golden age for dynamics with many advances possible. 

Undergraduate programs in engineering are demanding, time consuming, and inherently social endeavors for young adults. Strong social support networks and communities which foster success are frequently found to increase student retention and perseverance through their engineering degree programs. Students with marginalized identities in higher education are met with additional workloads – managing their social identity, negotiating stereotypes, and finding belonging. Existing research shows that a student’s experience in in higher education is particularly shaped by gender interactions. This has been shown to be particularly true in engineering, whose gender demographics and professional culture is described as hegemonically masculine. Research on gender in engineering has typically framed gender within a rigid, essentialized cisgender binary. Current literature is lacking detail on the processes used by gender diverse students in the transgender and gender nonconforming (TGNC) community as they navigate the gendered engineering field. We wish to highlight the experiences that undergraduate engineering students have had in relation to their social support and perceptions of gender as it relates to engineering culture within their undergraduate programs. Two students participated in autoethnography as a method of data collection to meet this objective. Collaborative autoethnographic methods position the students as coauthors and coresearchers to ensure the validity of analysis alongside the project’s primary investigators. Using a resiliency framework and critical autoethnographic analysis, the primary focus is on the ways these students have formed support systems and their perception of the social landscape in engineering. Through exploring how students persevere through their programs we may uncover points of intervention to strengthen these support systems. 

Abstract The Pixel Luminosity Telescope is a silicon pixel detector dedicated to luminosity measurement at the CMS experiment at the LHC. It is located approximately 1.75 m from the interaction point and arranged into 16 “telescopes”, with eight telescopes installed around the beam pipe at either end of the detector and each telescope composed of three individual silicon sensor planes. The per-bunch instantaneous luminosity is measured by counting events where all three planes in the telescope register a hit, using a special readout at the full LHC bunch-crossing rate of 40 MHz. The full pixel information is read out at a lower rate and can be used to determine calibrations, corrections, and systematic uncertainties for the online and offline measurements. This paper details the commissioning, operational history, and performance of the detector during Run 2 (2015–18) of the LHC, as well as preparations for Run 3, which will begin in 2022. 

Abstract Major sudden stratospheric warmings (SSWs), vortex formation, and final breakdown dates are key highlight points of the stratospheric polar vortex. These phenomena are relevant for stratosphere‐troposphere coupling, which explains the interest in understanding their future changes. However, up to now, there is not a clear consensus on which projected changes to the polar vortex are robust, particularly in the Northern Hemisphere, possibly due to short data record or relatively moderate CO₂forcing. The new simulations performed under the Coupled Model Intercomparison Project, Phase 6, together with the long daily data requirements of the DynVarMIP project in preindustrial and quadrupled CO₂(4xCO₂) forcing simulations provide a new opportunity to revisit this topic by overcoming the limitations mentioned above. In this study, we analyze this new model output to document the change, if any, in the frequency of SSWs under 4xCO₂forcing. Our analysis reveals a large disagreement across the models as to the sign of this change, even though most models show a statistically significant change. As for the near‐surface response to SSWs, the models, however, are in good agreement as to this signal over the North Atlantic: There is no indication of a change under 4xCO₂forcing. Over the Pacific, however, the change is more uncertain, with some indication that there will be a larger mean response. Finally, the models show robust changes to the seasonal cycle in the stratosphere. Specifically, we find a longer duration of the stratospheric polar vortex and thus a longer season of stratosphere‐troposphere coupling.